US 7,449,243 B1
Glass yarns, composite thereof, method for making same and reinforcing glass composition
Sophie Creux, La Motte Servolex (France); Michel Leclercq, La Motte Servolex (France); and Pascal Fournier, Chambery (France)
Assigned to Vetrotex France S.A., Chambery (France)
Appl. No. 10/129,265
PCT Filed Oct. 31, 2000, PCT No. PCT/FR00/03038
§ 371(c)(1), (2), (4) Date Sep. 30, 2002,
PCT Pub. No. WO01/32576, PCT Pub. Date May 10, 2001.
Claims priority of application No. 99 13836 (FR), filed on Nov. 04, 1999.
Int. Cl. B32B 17/06 (2006.01); C03C 13/00 (2006.01); B29C 53/00 (2006.01)
U.S. Cl. 428—426  [428/36.3; 501/35; 501/55; 501/68; 501/155; 264/13; 264/164; 65/126] 24 Claims
 
1. Reinforcing glass yarn, the composition of which comprises the following constituents, within the limits defined below, expressed in percentages by weight:
   
  SiO2 54.5 to 58%
  Al2O3 12 to 15.5%
  SiO2 + Al2O3 70 to 73%
  CaO 17 to 25%
  MgO 0 to 5%
  RO = CaO + MgO 21 to 28%
  R2O = Na2O + K2O + Li2O up to 2%
  TiO2 less than 1%
  Fe2O3 less than 0.5%
  B2O3 up to 3%
  F2 less than 1%
   
and such that the ratio R1=Al2O3/CaO is less than 0.7, and when SiO2 is greater than 57% the amount of boron oxide B2O3 is greater than 2%,
wherein the composition further satisfies the criterion:
2.35<R2=(SiO2+Al2O3)/(RO+R2O+B2O3)<2.70,
a T (log 2.5) of at least 1300° C.,
its liquidus temperature is less than or equal to 1200° C.,
and its fiberizing temperature range is greater than 100° C.