US 7,605,217 B2
High strength propylene-based elastomers and uses thereof
Sudhin Datta, Houston, Tex. (US); and Abdelhadi Sahnoune, Houston, Tex. (US)
Assigned to ExxonMobil Chemical Patents Inc., Houston, Tex. (US)
Filed on Nov. 12, 2004, as Appl. No. 10/988,162.
Claims priority of provisional application 60/519975, filed on Nov. 14, 2003.
Prior Publication US 2005/0131142 A1, Jun. 16, 2005
This patent is subject to a terminal disclaimer.
Int. Cl. C08F 210/18 (2006.01)
U.S. Cl. 526—339  [526/335; 526/281; 526/280; 525/331.7] 17 Claims
 
1. A crosslinked elastomer comprising:
(a) propylene-derived units in an amount of at least 75 wt %, based on the combined weight of components (a), (b), and (c);
(b) ethylene-derived units in an amount of at least 5 wt %, based on the combined weight of components (a), (b), and (c); and
(c) diene-derived units in an amount of from 0.3 to 10 wt %, based on the combined weight of components (a), (b), and (c); where the diene is selected from the group consisting of 5-ethylidene-2-norbornene, 5-vinyl-2-norbornene, divinyl benzene, and dicyclopentadiene; and
wherein the elastomer has an isotactic propylene triad tacticity of from 65 to 95%, a melting point by DSC equal to or less than 110° C., a heat of fusion of from 5 J/g to 50 J/g, an ultimate tensile strength of 1 MPa or greater, a Die C tear strength of 50 lb/in or greater, and a ratio of Shore A hardness to MFR@230° C. prior to crosslinking of 160 or less.