US 7,527,884 B2
Fuel processing system and its shutdown procedure
Motohisa Kamijo, Kanagawa (Japan)
Assigned to Nissan Motor Co., Ltd., Kanagawa-Ken (Japan)
Filed on Mar. 14, 2005, as Appl. No. 11/78,391.
Prior Publication US 2006/0204800 A1, Sep. 14, 2006
Int. Cl. H01M 8/18 (2006.01); H01M 8/04 (2006.01); C01B 3/12 (2006.01); B01J 11/00 (2006.01); B01J 8/04 (2006.01)
U.S. Cl. 429—20  [429/17; 423/655; 422/189; 422/190; 422/198] 12 Claims
OG exemplary drawing
 
11. In a fuel cell system that includes at least one water gas shift reactor, a fuel reformer upstream of the water gas shift reactor, at least one preferential oxidation reactor downstream of the water gas shift reactor, and at least one fuel cell downstream of the preferential oxidation reactor,
a method of shutting down the fuel cell system, the method comprising the steps of:
shutting down a supply of reformate from the fuel reformer to the water gas shift reactor to start a shutdown procedure of electrical generation of the fuel cell;
monitoring a temperature of at least one of the fuel reformer, the water gas shift rector and the preferential oxidation reactor;
supplying air to the water gas shift reactor and also to the preferential oxidation reactor in response to the monitored temperature after the shutdown procedure of electrical generation of the fuel cell has been started at a quantity such that the temperature of each of the water gas shift reactor and the preferential oxidation reactor is lower than a maximum working temperature of the reactor; and
transferring heat generated due to oxidation by the supplied air within the fuel reformer and the water gas shift reactor to the preferential oxidation reactor by supplying vaporized water to upstream of the water gas shift reactor in response to the monitored temperature after the shutdown procedure of electrical generation of the fuel cell has been started in order to maintain the temperature within the preferential oxidation reactor high enough for oxidation reaction to proceed.