US 7,473,724 B2
Preparation of silica reinforced polyisoprene-rich rubber composition and tire with component thereof
Wen-Liang Hsu, Cuyahoga Falls, Ohio (US); Shingo Futamura, Wadsworth, Ohio (US); Kenneth Allen Bates, Brunswick, Ohio (US); Adel Farhan Halasa, Bath, Ohio (US); Kuo-Chih Hua, Richfield, Ohio (US); and Bruce Raymond Hahn, Hudson, Ohio (US)
Assigned to The Goodyear Tire & Rubber Company, Akron, Ohio (US)
Filed on Feb. 15, 2005, as Appl. No. 11/58,531.
Prior Publication US 2006/0183831 A1, Aug. 17, 2006
Int. Cl. C08K 5/15 (2006.01)
U.S. Cl. 524—114  [524/385] 17 Claims
 
1. A process of preparing a rubber composition which comprises the steps of:
(A) blending, based upon parts by weight per 100 parts by weight rubber (phr):
(1) 100 phr of at least one conjugated diene-based elastomer consisting essentially of:
(a) from about 50 to about 100 phr of dry cis 1 ,4-polyisoprene rubber, and
(b) from zero to about 50 phr of at least one additional conjugated diene-based elastomer selected from at least one of cis 1,4-polybutadiene rubber, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, styrene-isoprene rubber, isoprene-butadiene rubber and high vinyl-polybutadiene rubber having a vinyl 1,2- content in a range of from about 30 to about 80 percent,
(2) from about 25 to about 120 phr of reinforcing filler comprised of:
(a) from about 20 to about 115 phr of precipitated silica aggregates, and
(b) from about 5 to about 70 phr of rubber reinforcing carbon black, and
(B) thereafter adding and blending sulfur curative therewith; characterized in that said precipitated silica aggregates are treated with a modifier selected from a fatty alcohol and epoxidized soybean oil and their mixtures in the absence of and prior to said addition of said sulfur curative addition by pre-treating said precipitated silica aggregates with said modifier to form a pre-formed silica/modifier composite as a reaction product thereof and blending said pre-formed silica/modifier composite with said conjugated diene-based elastomer(s), followed by reacting said pre-formed silica/modifier composite with a coupling agent in situ within said conjugated diene-based elastomer(s) to form a silica/modifier/coupling agent composite thereof
wherein said fatty alcohol is selected from at least one of 1 -octanol, 1 -decanol, 1 -dodecanol, 1 -tetradecanol, 1 -hexadecanol, 1 -octadecanol, 1 -eicosanol, 1 -docosanol, 1 -tetracosanol, 1-hexacosanol, or 1 -octacosanol, and their mixtures;
wherein said coupling agent is selected from bis(ω-trialkoxysilylalkyl) polysulfide having an average of from about 2 to about 4 connecting sulfur atoms in its polysulfidic bridge, or ω-mercaptoalkyltrialkoxysilane, or ω-mercaptoalkyltrialkoxysilane having its mercapto moiety blocked from pre-reacting with hydroxyl groups contained on said precipitated silica aggregates prior to unblocking said blocked mercapto moiety.